Journal of Organic Chemistry p. 918 - 920 (1988)
Update date:2022-08-02
Topics:
Hatanaka, Yasuo
Hiyama, Tamejiro
In the presence of tris(diethylamino)sulfonium difluorotrimethylsilicate (TASF) and allylpalladium chloride dimer as a catalyst, organosilicon compounds like vinyl-, ethynyl-, and allylsilanes react with such organic halides as aryl, vinyl, and allyl halides to give the corresponding coupled products in synthetically useful yields in a stereospecific and chemoselective manner.
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