111470-22-5Relevant academic research and scientific papers
Thermolysereaktionen der donorfreien silanimine tBu2Si=N- SiRtBu2 (R = tBu, Ph): Thermolysis reactions of donor-free silanimines tBu2Si=N-SiRtBu2 (R = tBu, Ph)
Lerner, Hans-Wolfram,Saenger, Inge,Bolte, Michael,Wagner, Matthias
experimental part, p. 72 - 78 (2010/07/08)
The donor-free silanimines tBu2Si=N-SiRtBu2 (R = tBu Ph) which are prepared from tBu2ClSiN3 and NaSiRtBu 2 at -78 °C inBu2O decompose in benzene at room temperature with the formation of isobutene. Pr
On the Stable Silanimine tBu2Si=N-SitBu3 and of Its Donor Adducts
Wiberg, Nils,Schurz, Klaus
, p. 581 - 590 (2007/10/02)
Pale yellow, solid silanimine tBu2Si=N-SitBu3 (3), metastable at normal conditions and extremely sensitive to water, is prepared by reaction of tBu3SiNa and tBu2SiClN3 in dibutyl ether at about -50 deg C.It forms adducts 3*D with donors D (coordination wi
