1114884-11-5

Basic information

• Product Name: 2-((1S,2R)-2-(4-chlorophenyl)-2-(4,4-dimethylpent-2-ynoyl)cyclopropyl)isoindoline-1,2-dione
• Synonyms: 2-((1S,2R)-2-(4-chlorophenyl)-2-(4,4-dimethylpent-2-ynoyl)cyclopropyl)isoindoline-1,2-dione
• CAS NO: 1114884-11-5
• Molecular Weight: 405.881
• Mol File: 1114884-11-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-((1S,2R)-2-(4-chlorophenyl)-2-(4,4-dimethylpent-2-ynoyl)cyclopropyl)isoindoline-1,2-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 2-((1S,2R)-2-(4-chlorophenyl)-2-(4,4-dimethylpent-2-ynoyl)cyclopropyl)isoindoline-1,2-dione(1114884-11-5)
• EPA Substance Registry System: 2-((1S,2R)-2-(4-chlorophenyl)-2-(4,4-dimethylpent-2-ynoyl)cyclopropyl)isoindoline-1,2-dione(1114884-11-5)

Safety Data

• Hazardous Substances Data: 1114884-11-5(Hazardous Substances Data)

Upstream product

• 3485-84-5 N-vinylphthalimide 
• 1114884-05-7 1-(4-chlorophenyl)-1-diazo-5,5-dimethylhex-3-yn-2-one 

Relevant articles and documents

Enantioselective reactions of donor/acceptor carbenoids derived from α-aryl-α-diazoketones

The reaction of a variety of α-aryl-α-diazo ketones with activated olefins, catalyzed by the adamantyl glycine-derived dirhodium complex Rh2(S-PTAD)4, generates cyclopropyl ketones with high diastereoselectivity (up to >95:5 dr) and enantioselectivity (up to 98% ee). Intermolecular C-H functionalization of 1,4-cyclohexadiene by means of carbenoid-induced C-H insertion was also possible with this type of carbenoid.