111506-76-4

Upstream product

• 17049-49-9 octylmagnesium bromide 
• 105983-23-1 (2S)-1,2-epoxy-3-phenylsulphonylpropane 
• 111506-75-3 (2R)-1-chloro-3-phenylsulphonylpropan-2-ol 
• 108-98-5 thiophenol 
• 22198-54-5 1-chloro-3-phenylsulfanylpropan-2-one 
• 23886-96-6 1-chloro-3-phenylsulphonylpropane-2-one 

Downstream Products

• 111533-80-3 (3S,5R,6S)-3,6-epoxy-5-phenylsulphonylpentadec-1-ene 
• 111533-79-0 (3R,5R,6S)-3,6-epoxy-5-phenylsulphonylpentadec-1-ene 
• 112370-43-1 Toluene-4-sulfonic acid (2R,3S)-2-benzenesulfonyl-3-hydroxy-dodecyl ester 
• 111533-66-5 (2S,3R)-3-Benzenesulfonyl-2-nonyl-5-(1-phenylselanyl-ethyl)-tetrahydro-furan 
• 111533-52-9 (5R,6S)-5-phenylsulphonylpentadec-2-en-6-ol 
• 111533-52-9 (5S,6S)-5-phenylsulphonylpentadec-2-en-6-ol 
• 112370-48-6 (2R,3S)-2-Benzenesulfonyl-dodecane-1,3-diol 

Relevant academic research and scientific papers

Synthesis of Enantiomerically Pure 2,5-Disubstituted Teterahydrofurans Using Readily Prepared (2S)-1-Phenylsulphonylalkan-2-ols

Enantiomerically pure (2S)-1-phenylsulphonylalkan-2-ols have been prepared from 1-chloro-3-phenylsulphonylpropan-2-one (2) by the folloving successive procedures: reduction with baker's yeast, epoxidation with silver(I) oxide, and alkylation with

Reactions of (2S)-1-Arenesulfonyl-2-alkanol Dianions with Aldehydes. Application to the Synthesis of Enantiomerically Pure (3S)-1-Alken-3-ols and (2E,4S)-4-hydroxy-2-alkenenitriles

Enantiomerically pure (2S)-1-arenesulfonyl-2-alkanols (1) were prepared by yeast reduction of 1-arenesulfonyl-3-chloro-2-propanones, followed by epoxydation and alkylation.Reaction of dianions of 1 with aldehydes occurred at the pro(R) position of C(1) to give 1,3-diols, which were converted to (3S)-1-alken-3-ols or (2E,4S)-4-hydroxy-2-alkenenitriles in 100percent e.e.