111506-75-3

Upstream product

• 23886-96-6 1-chloro-3-phenylsulphonylpropane-2-one 
• 930-69-8 sodium thiophenolate 
• 108-98-5 thiophenol 
• 22198-54-5 1-chloro-3-phenylsulfanylpropan-2-one 

Downstream Products

• 105983-24-2 (S)-1-Phenylsulphonyldecan-2-ol 
• 111506-77-5 (2S)-1-phenylsulphonylpentadecan-2-ol 
• 112370-49-7 (2R,3S)-2-Benzenesulfonyl-undecane-1,3-diol 
• 112370-48-6 (2R,3S)-2-Benzenesulfonyl-dodecane-1,3-diol 
• 111533-66-5 (2S,3R)-3-Benzenesulfonyl-2-nonyl-5-(1-phenylselanyl-ethyl)-tetrahydro-furan 
• 111533-68-7 (2S,3R)-3-Benzenesulfonyl-5-(1-phenylselanyl-ethyl)-2-tridecyl-tetrahydro-furan 
• 112370-43-1 Toluene-4-sulfonic acid (2R,3S)-2-benzenesulfonyl-3-hydroxy-dodecyl ester 
• 111533-44-9 (2S,3R)-3-phenylsulphonylhept-5-en-2-ol 
• 111533-44-9 (2S,3S)-3-phenylsulphonylhept-5-en-2-ol 
• 111533-72-3 (2S,3R,5R)-2,5-epoxy-3-phenylsulphonylhept-6-ene 
• 111533-73-4 (2S,3R,5S)-2,5-epoxy-3-phenylsulphonylhept-6-ene 
• 111533-89-2 (2S,3S,5R)-2,5-epoxy-3-phenylsulphonylhept-6-ene 
• 111533-90-5 (2S,3S,5S)-2,5-epoxy-3-phenylsulphonylhept-6-ene 
• 111506-76-4 (2S)-1-phenylsulphonylundecan-2-ol 

Relevant academic research and scientific papers

Enantioselective hydrogenation of β-keto sulfones with chiral Ru(II)- catalysts: Synthesis of enantiomerically pure butenolides and γ- butyrolactones

A series of β-hydroxy sulfones were synthesized with high enantioselectivities via a new enantioselective ruthenium-catalyzed hydrogenation using MeO-BIPHEP as a ligand. Some β-hydroxy sulfones were used in the synthesis of optically active butenolides and γ-butyrolactones with high yields and enantioselectivities over 95%.

Synthesis of Enantiomerically Pure (4S)-2-Alken-4-olides via (2S)-1-Phenylsulfonyl-2-alkanols

Reduction of 1-chloro-3-phenylsulfonyl-2-propanone with baker's yeast, followed by epoxidation and alkylation with Grignard reagents, yields enantiomerically pure (2S)-2-phenylsulfonyl-2-alkanols, which are converted into (4S)-2-alken-4-olides in 100perce

Synthesis of Enantiomerically Pure 2,5-Disubstituted Teterahydrofurans Using Readily Prepared (2S)-1-Phenylsulphonylalkan-2-ols

Enantiomerically pure (2S)-1-phenylsulphonylalkan-2-ols have been prepared from 1-chloro-3-phenylsulphonylpropan-2-one (2) by the folloving successive procedures: reduction with baker's yeast, epoxidation with silver(I) oxide, and alkylation with

Reactions of (2S)-1-Arenesulfonyl-2-alkanol Dianions with Aldehydes. Application to the Synthesis of Enantiomerically Pure (3S)-1-Alken-3-ols and (2E,4S)-4-hydroxy-2-alkenenitriles

Enantiomerically pure (2S)-1-arenesulfonyl-2-alkanols (1) were prepared by yeast reduction of 1-arenesulfonyl-3-chloro-2-propanones, followed by epoxydation and alkylation.Reaction of dianions of 1 with aldehydes occurred at the pro(R) position of C(1) to give 1,3-diols, which were converted to (3S)-1-alken-3-ols or (2E,4S)-4-hydroxy-2-alkenenitriles in 100percent e.e.