1116155-89-5

Basic information

• Product Name: 2-bromophenyl (4-methoxyphenyl)diisopropylsilyl ether
• Synonyms: 2-bromophenyl (4-methoxyphenyl)diisopropylsilyl ether
• CAS NO: 1116155-89-5
• Molecular Weight: 393.396
• Mol File: 1116155-89-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-bromophenyl (4-methoxyphenyl)diisopropylsilyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromophenyl (4-methoxyphenyl)diisopropylsilyl ether(1116155-89-5)
• EPA Substance Registry System: 2-bromophenyl (4-methoxyphenyl)diisopropylsilyl ether(1116155-89-5)

Safety Data

• Hazardous Substances Data: 1116155-89-5(Hazardous Substances Data)

Upstream product

• 347904-48-7 chloro(4-methoxyphenyl)diisopropylsilane 
• 95-56-7 2-hydroxybromobenzene 

Downstream Products

• 1116155-90-8 2-[(4-methoxyphenyl)diisopropylsilyl]phenol 

Relevant articles and documents

Modular approach to silicon-bridged biaryls: Palladium-catalyzed intramolecular coupling of 2-(arylsilyl)aryl triflates

(Chemical Equation Presented) Bridge of Si: Intramolecular direct arylation of 2-(arylsilyl)aryl triflates is catalyzed smoothly by Pd(OAc) 2/PCy3 in the presence of Et2NH in dimethylacetamide (DMA), giving rise to the corresponding silicon-bridged biaryls in good to excellent yields. The new approach has led to the synthesis of a silicon-bridged 2-phenylindole (see scheme) that exhibits blue photoluminescence in the solid state with extremely high quantum yields.