347904-48-7Relevant academic research and scientific papers
Synthesis of Benzosiloles by Intramolecular anti-Hydroarylation via ortho-C-H Activation of Aryloxyethynyl Silanes
Minami, Yasunori,Noguchi, Yuta,Hiyama, Tamejiro
, p. 14013 - 14016 (2017/10/17)
Straightforward synthesis of benzosiloles was achieved by the invention of Pd/acid-catalyzed intramolecular anti-hydroarylation of aryloxyethynyl(aryl)silanes via ortho-C-H bond activation. The aryloxy group bound to the ethynyl carbon is the key factor for this transformation.
Formation of carbocycles via a 1,4-Rh shift triggered by a rhodium-catalyzed addition of terminal alkynes to 3,3-diarylcyclopropenes
Sawano, Takahiro,Hashizume, Minoru,Nishimoto, Shouta,Ou, Keiyu,Nishimura, Takahiro
supporting information, p. 2630 - 2633 (2015/06/16)
The catalytic addition of terminal alkynes to 3,3-diarylcyclopropenes in the presence of a Rh(I)/binap complex proceeded to give the cycloaddition products in good yields, where a 1,4-Rh shift is involved as a key step.
Dihydropyrancarboxamides and uses thereof
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, (2010/02/06)
The present invention provides novel dihydropyrancarboxamide compounds of formula (I): 1and collections of these compounds, and provides methods for the synthesis of these compounds; wherein R1-R6 are as defined herein. Additionally
