111734-91-9

Upstream product

• 111734-90-8 {(3R,5S,6S)-6-[(E)-(R)-4-(1-Ethoxy-ethoxy)-1-methyl-but-2-enyl]-2-hydroxy-3,5-dimethyl-tetrahydro-pyran-2-ylmethyl}-phosphonic acid dimethyl ester 
• 824-94-2 p-methoxybenzyl chloride 
• 103563-59-3 (3R,5S,6S)-6-[(E)-(R)-4-(1-Ethoxy-ethoxy)-1-methyl-but-2-enyl]-3,5-dimethyl-tetrahydro-pyran-2-one 

Downstream Products

• 111734-92-0 (E)-(4S,5S,6S,8R)-10-(Dimethoxy-phosphoryl)-5-(4-methoxy-benzyloxy)-4,6,8-trimethyl-9-oxo-dec-2-enoic acid 
• 111734-93-1 (E)-(4S,5S,6S,8R)-10-(Dimethoxy-phosphoryl)-5-(4-methoxy-benzyloxy)-4,6,8-trimethyl-9-oxo-dec-2-enoic acid (E)-(1R,2R)-1-ethyl-2-(4-methoxy-benzyloxymethyl)-5-oxo-pent-3-enyl ester 
• 111734-94-2 (3E,11E,13E)-(5S,6S,7S,9R,15R,16R)-16-Ethyl-6-(4-methoxy-benzyloxy)-15-(4-methoxy-benzyloxymethyl)-5,7,9-trimethyl-oxacyclohexadeca-3,11,13-triene-2,10-dione 
• 77704-61-1 Myconolide IV 

Relevant academic research and scientific papers

Stereocontrolled First Total Synthesis of Mycinolide IV

First total synthesis of mycinolide IV (2) was accomplished.Novel rearrangement of epoxyalcohol derivatives was applied to the synthesis of the C(11)-C(17) portion, assembly of wich with the C(1)-C(10) portion (prepared via pinacol-type rearrangement) ena