Stereocontrolled First Total Synthesis of Mycinolide IV

DOI: 10.1246/cl.1987.113

Source and publish data:

Chemistry Letters p. 113 - 116 (1987)

Update date:2022-08-04

Topics:

Authors:

Suzuki, Keisuke

Matsumoto, Takashi

Tomooka, Katsuhiko

Matsumoto, Kazutsugu

Tsuchihashi, Gen-ichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1987.113

First total synthesis of mycinolide IV (2) was accomplished.Novel rearrangement of epoxyalcohol derivatives was applied to the synthesis of the C(11)-C(17) portion, assembly of wich with the C(1)-C(10) portion (prepared via pinacol-type rearrangement) ena

Full text of DOI:10.1246/cl.1987.113

Products guided by the article

Product name:[(E)-(3R,5S,6S,7S)-10-(1-Ethoxy-ethoxy)-6-(4-methoxy-benzyloxy)-3,5,7-trimethyl-2-oxo-dec-8-enyl]-phosphonic acid dimethyl ester

Cas No:111734-91-9

R&D Labs maybe for 111734-91-9

SHENZHEN PENGCHENG REDSTAR INDUSTRY CO.,LTD

Contact:+86-755-82412922

Address:Room 8066, East Block, Square City, Jiabin Road, Luohu District
Zibo Jujin Chemical Industry Co., Ltd.（Dongming Jujin Chemical Industry Co., Ltd. ）

Contact:+86-533-2975022

Address:No.99 Shanquan Road, Zhangdian District
Shandong Topscience Biotech Co., Ltd.

Contact:0633-2619278

Address:No. 98 Lanshan West Road, Lanshan District, Rizhao, Shandong Province, P.R. of China
Tianjin Jiuri New Materials Co., Ltd.

Contact:+86-22-58889220

Address:C-5/6, Vison Hill, No.1 Gonghua Road, Huayuan Hi-tech Park, Tianjin, China.
ZK Biochem Group Co., Ltd

Contact:+86-532-80762375

Address:No. 6, Hongkong Middle Road, Qingdao, China

Relevant to this article

Different coordination behavior of a catechol phosphine and its sulfide: Formation of an unprecedented dinuclear rhodium complex with a non-coordinated PS unit

Doi:10.1016/j.ica.2011.02.076
(2011)
Characterization of a new class of selective nonsteroidal progesterone receptor agonists

Doi:10.1016/j.steroids.2003.12.007
(2004)
Iodine-Promoted Rapid Construction of Carbamoylphosphonates from Phosphinecarboxamides

Doi:10.1002/adsc.201800303
(2018)
18-Functionalized steroids: synthesis of thioderivatives of progesterone

Doi:10.1016/0039-128X(90)90044-C
(1990)
Synthesis of 4- and 16α-hydroxylated equine estrogens

Doi:10.1016/0039-128X(90)90039-E
(1990)
Transition-metal-free synthesis of vinyl sulfones via tandem cross-decarboxylative/coupling reactions of sodium sulfinates and cinnamic acids

Doi:10.1039/c4gc00542b
(2014)

Article Doi