111833-84-2Relevant academic research and scientific papers
TOTAL SYNTHESIS OF D,L-PURPUROSAMINE C
Golebiowski, Adam,Jacobsson, Ulla,Chmielewski, Marek,Jurczak, Janus
, p. 599 - 605 (2007/10/02)
Methyl 2,6-diacetamido-2,3,4,6-tetradeoxy-α-D,L-erythropyranoside (methyl 2,6-N,N-diacetyl-D,L-purpurosamidine C) was synthesized from N-tert-butoxycarbonylaminoethanol and l-methoxybuta-1,3-diene in a seven-step reaction sequence. (4+2)Cycloaddition of diene 1 to N-protected α-amino aldehyde 2 and hydroboration of the adduct formed are key steps in the synthetic sequence.
