111860-07-2Relevant academic research and scientific papers
A CONVERGENT TOTAL SYNTHESIS OF (-)-ANAMARINE FROM D-GLUCOSE
Lichtenthaler, Frieder W.,Lorenz, Klaus,Ma, Wei-yong
, p. 47 - 50 (2007/10/02)
The di-acetonide of 6-deoxy-aldehydo-D-glucose 12 and (S,S)-2-ethoxy-6-triphenylphosphoniomethyl-dihydropyran iodide 8 are elaborated from D-glucose each in practicable procedures of 5 and 10 steps, resp., and subsequently joined to give, after oxidation, deprotection and acetylation, (-)-anamarine (ent-1).The synthesis proves the absolute configuration of natural (+)-anamarine (1).
