111865-50-0Relevant academic research and scientific papers
Efficient synthesis of homoallylic alcohols/amines from allyltributylstannane and carbonyl compounds/imines using iodine as catalyst under acetic acid-water medium
Kalita, Pabitra Kumar,Borthakur, Susanta Kumar,Das, Runumi,Choudhury, Chandan Jyoti
, p. 2444 - 2453 (2015)
This paper describes a general method for the synthesis of homoallylic alcohols and amines by nucleophilic addition reaction of allyltributylstannane to carbonyl compounds and aldimines where iodine acts as a catalyst in H2O/acetic acid (1:1) medium. Only 10 mol% of I2 is required for various organic transformations. By using this process, various homoallylic alcohols and amines are produced in good to excellent yields.
A three-component synthesis of homoallylic amines catalyzed by CuI
Kalita, Pabitra Kumar,Phukan, Prodeep
, p. 5495 - 5497 (2008/12/22)
Cuprous iodide is a very effective catalyst for the three-component condensation of an aldehyde, benzylamine and allyltributylstannane in DMF to produce homoallylic amines in high yields.
ELECTROREDUCTIVE "BARBIER TYPE" ALLYLATION OF IMINES WITH A COMBINATION OF A Pb(O)/Pb(II) REDOX MEDIATOR AND SACRIFICAL ANODE (Al)
Tanaka, Hideo,Nakahara, Takao,Dhimane, Hamid,Torii, Sigeru
, p. 4161 - 4164 (2007/10/02)
An electroreductive "Barbier Type" allylation of imines with allyl bromide has been performed in a PbBr2/Bu4NBr/THF-(Al anode)-(Pt cathode) system.A combination of Pb(O)/Pb(II) redox and a sacrifical aluminum anode works as a madiator for both cathodic an
Allylation of Imines with in situ Generated Allyl Lead Reagents in a PbBr2/Al/BF3*OEt2/Et2O System
Tanaka, Hideo,Yamashita, Shiro,Ikemoto, Youichi,Torii, Sigeru
, p. 673 - 674 (2007/10/02)
Reductive addition of allyl bromide to imines has been performed with a combination of a catalytic amount of PbBr2 (0.03-0.1 equiv.) and Al (1 equiv.) in Et2O containing BF3*OEt2 (1.1 equiv.).
