Synthetic Communications p. 2444 - 2453 (2015)
Update date:2022-08-04
Topics:
Kalita, Pabitra Kumar
Borthakur, Susanta Kumar
Das, Runumi
Choudhury, Chandan Jyoti
This paper describes a general method for the synthesis of homoallylic alcohols and amines by nucleophilic addition reaction of allyltributylstannane to carbonyl compounds and aldimines where iodine acts as a catalyst in H2O/acetic acid (1:1) medium. Only 10 mol% of I2 is required for various organic transformations. By using this process, various homoallylic alcohols and amines are produced in good to excellent yields.
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