111914-72-8Relevant articles and documents
Carbonylation of Aryl Halides and Vinyl Bromides Mediated by Tetracarbonylcobalt Anion
Miura, Masahiro,Akase, Fumiaki,Shinohara, Masato,Nomura, Masakatsu
, p. 1021 - 1026 (2007/10/02)
The reaction of aryl halides (1a-g) with octacarbonyldicobalt in the presence of methyl iodide and sodium hydroxide under phase-transfer conditions was found to give a mixture of aryl methyl ketones (2a-g) and aromatic carboxylic acids (3a-h).From vinyl halides (9a-c), however, the corresponding carboxylic acids (10a-c) were obtained exclusively.