111963-40-7Relevant academic research and scientific papers
Functionalized nitrogen-containing tertiary phosphine oxides
Varbanov,Tosheva,Russeva
, p. 27 - 37 (2007/10/03)
Several new functionalized tertiary phosphine oxides, namely o-, m-and p-dimethylphosphinyl-methyleneoxyanilines, bis(dimethylphosphinylmethylene)amine and N-dimethylphosphinylmethy-lene-∈-caprolactam have been synthesized. These compounds were prepared via alkylation of o-, m-and p-atninosubstituted sodium phenolates, aminomethyldimethylphosphine oxide and sodium salt of ∈-caprolactam with chloromethyldimethylphosphine oxide. The m-and p-dimethylphosphi-nylmethyleneoxyanilines and aminomethyldimethylphosphine oxide were acylated with benzoylchloride to the corresponding amides. The new compounds were chatacterized by analytical methods, IR, 1H-and 31P{H}-NMR spectroscopy.
PHOSPHANE OXIDES AS INTERMEDIATES IN THE SYNTHESIS OF POTENTIALLY BIOACTIVE COMPOUNDS
Matolcsy, Gyoergy,Bauer, Krisztina,Pal, Agnes,Ujvary, Istvan,Belai, Ivan,et al.
, p. 145 - 154 (2007/10/02)
New chloromethylphosphane oxides, as well as phosphane oxide-substituted benzyl alcohols, benzaldehydes, aromatic nitro compounds, anilines, and phenols were synthesized as intermediates for the introduction of the phosphane oxide function into bioactive
