112013-75-9Relevant academic research and scientific papers
Lithio Styryl Sulfone as an Acyl Anion Synthon
Yamamoto, Makoto,Suzuki, Kazuya,Tanaka, Seiji,Yamada, Kazutoshi
, p. 1523 - 1524 (2007/10/02)
Lithio styryl sulfone, which was shown to be an acyl anion synthon, reacted with various electrophiles; the products were rearranged by treatments with m-chloroperbenzoic acid to give acyl benzyl sulfones in good yields.
ELECTRON-TRANSFER PROCESSES IN THE ALKYLATION OF α,β-UNSATURATED SULFONES BY ORGANOMETALLIC REAGENTS
Eisch, John J.,Behrooz, Mohammad,Galle, James E.
, p. 4851 - 4854 (2007/10/02)
The alkyldesulfonylation of acetylenic and vinylic sulfones by organolithium and organomagnesium reagents is shown to take place via alkyl radicals arising from electrontransfer processes.
