112013-78-2

Upstream product

• 5324-64-1 2-(benzenesulfonyl)ethynylbenzene 
• 688-73-3 tri-n-butyl-tin hydride 
• 16212-06-9 phenyl styryl sulfone 
• 1461-22-9 tributyltin chloride 

Downstream Products

• 1581883-43-3 (Z)-1-phenyl-2-phenylsulfonyldec-1-en-3-yne 
• 929696-68-4 (1Z,3E)-1,4-diphenyl-2-phenylsulfonyl-1,3-butadiene 
• 112013-76-0 C₁₈H₂₀O₂S 
• 72568-87-7 C₂₁H₁₈O₂S 
• 112013-75-9 C₁₄H₁₁LiO₂S 
• 112013-79-3 1-(benzenesulfonyl)-1-phenylpropan-2-one 
• 19232-53-2 (E)-1,3-diphenyl-2-(phenylsulfonyl)prop-2-en-1-one 
• 30246-74-3 {[(1E)-1-phenylprop-1-en-2-yl]sulfonyl}benzene 
• 16212-06-9 phenyl styryl sulfone 

Relevant academic research and scientific papers

Highly regio-and stereoselective synthesis of (1Z,3E)-2-sulfonyl-3-stannyl- 1,3-dienes by hydrostannylation of (Z)-2-sulfonyl-1,3-enynes

The Stille coupling of (E)-α-stannylvinyl sulfones with alkynyl bromides in DMF in the presence of Pd(PPh3)4 and CuI gave (Z)-2-sulfonyl-1,3- enynes in good yields. (Z)-2-Sulfonyl-1,3-enynes underwent palladium-catalysed hydrostannylation with tributyltin hydride to afford highly regio-and stereoselectively (1Z,3E)-2-sulfonyl-3-stannyl-1,3-dienes.

A facile stereoselective synthesis of (Z)-α-arylsulfonyl-α,β-unsaturated ketones

Palladium-catalyzed hydrostannylation of acetylenic sulfones 1 in benzene at room temperature gives highly regio- and stereoselectively (E)-α-stannylvinyl sulfones 2 in high yields. (E)-α-Stannylvinyl sulfones 2 are new difunctional group reagents which u

A facile stereoselective synthesis of 1,3-dienyl sulfones via Stille coupling reactions of (E)-α-stannylvinyl sulfones with alkenyl iodides

Palladium-catalyzed hydrostannylation of acetylenic sulfones 1 in benzene at room temperature gives stereoselectively (E)-α-stannylvinyl sulfones 2 in good yields. (E)-α-Stannylvinyl sulfones 2 are new difunctional group reagents which undergo Stille coup

Lithio Styryl Sulfone as an Acyl Anion Synthon

Lithio styryl sulfone, which was shown to be an acyl anion synthon, reacted with various electrophiles; the products were rearranged by treatments with m-chloroperbenzoic acid to give acyl benzyl sulfones in good yields.