112043-52-4Relevant academic research and scientific papers
AN IMPROVED PROCEDURE FOR THE CONVERSION OF 3,3-DISUBSTITUTED-1,4-CYCLOHEXADIENES TO 2,5-CYCLOHEXADIEN-1-ONES
Schultz, Arthur G.,Taveras, Arthur G.,Harrington, Roger E.
, p. 3907 - 3910 (2007/10/02)
The bis-allylic oxidations of 1,4-cyclohexadienes with tert-butyl hydroperoxide and pyridinium dichromate give 2,5-cyclohexadien-1-ones in good to excellent yields.
Intramolecular Cycloadditions to Oxyallyl Zwitterions Generated from Photorearrangements of 2,5-Cyclohexadien-1-ones
Schultz, Arthur G.,Macielag, Mark,Plummer, Mark
, p. 391 - 395 (2007/10/02)
Photorearrangement of 2,5-cyclohexadien-1-one 9a gave phenols 12 and 13, while 9b gave bicyclohexenone 10b.No evidence for the formation of an azide-zwitterion cycloadduct was obtained from these examples.However, the 3,6-dimethoxy analogue 9c provided the bridged triazene 14, for which X-ray crystallographic studies confirmed structural assignments for 14 and previously obtained triazenes 5a and 5b. 4--3-methoxy-4-(nethoxycarbonyl)cyclohexa-2,5-dien-1-one (17) photorearranged to bicyclohexenone 18 and phenol 19.The 4-acetoxymethyl derivatives 20a and 20b gave the bridged furan adducts 23a, and 23b in excellent yield.Acetoxymethyl-substituted triazene 27 was obtained from 26c; 27 slowly gave alcohol 28 on exposure to the atmosphere.
