112043-51-3

Upstream product

• 108-24-7 acetic anhydride 
• 112043-50-2 3-(3-chloropropyl)-3-(hydroxymethyl)-1,5-dimethyl-1,4-cyclohexadiene 
• 111112-92-6 3-(3-chloropropyl)-3-(methoxycarbonyl)-1,5-dimethyl-1,4-cyclohexadiene 

Downstream Products

• 112043-52-4 4-(acetoxymethyl)-4-(3-chloropropyl)-2,6-dimethyl-2,5-cyclohexadienone 

Relevant academic research and scientific papers

Intramolecular Cycloadditions to Oxyallyl Zwitterions Generated from Photorearrangements of 2,5-Cyclohexadien-1-ones

Photorearrangement of 2,5-cyclohexadien-1-one 9a gave phenols 12 and 13, while 9b gave bicyclohexenone 10b.No evidence for the formation of an azide-zwitterion cycloadduct was obtained from these examples.However, the 3,6-dimethoxy analogue 9c provided the bridged triazene 14, for which X-ray crystallographic studies confirmed structural assignments for 14 and previously obtained triazenes 5a and 5b. 4--3-methoxy-4-(nethoxycarbonyl)cyclohexa-2,5-dien-1-one (17) photorearranged to bicyclohexenone 18 and phenol 19.The 4-acetoxymethyl derivatives 20a and 20b gave the bridged furan adducts 23a, and 23b in excellent yield.Acetoxymethyl-substituted triazene 27 was obtained from 26c; 27 slowly gave alcohol 28 on exposure to the atmosphere.