112067-92-2Relevant academic research and scientific papers
PREVENTION OF CHELATION BY AN OXYGENE FUNCTION THROUGH PROTECTION WITH A TRIISOPROPYL SILYL GROUP
Frye, Stephen V.,Eliel, Ernest L.
, p. 3223 - 3226 (2007/10/02)
In contrast to other α- and β-alkoxy substituents the triisopropylsilyloxy group does not depress the high diastereomer excess normally realized in nucleophilic addition to 2-acyl-1,3-oxathianes.
ASYMMETRIC SYNTHESES BASED ON HEXAHYDRO-4,4,7-TRIMETHYL-1,3-BENZOXATHIANS
Eliel, Ernest L.
, p. 73 - 96 (2007/10/02)
Earlier work concerned with a highly stereoselective asymmetric synthesis based on a 1,3-oxathiane as the chiral auxiliary reagent is reviewed and recent applications to the synthesis of the four stereoisomers of malyngolide, of (R)-(+)-γ-caprolactone (a
