112078-88-3Relevant academic research and scientific papers
Preparation, Nuclear Magnetic Resonance Spectra, and X-Ray Diffraction Study of Bis(N-benzylacetimidic acid ethyl ester)dichloropalladium(II)
McCullough, Kevin J.,Bladon, Peter,Janecki, Tomasz,Pauson, Peter
, p. 2503 - 2504 (1987)
N-Benzylacetimidic acid ethyl ester (L) yields a stable complex of the type trans- with the nitrogen atoms as ? donors.This is not readily convertible to an ortho-palladated complex.An X-ray crystallographic study reveals a centrosymmetric structure 1/c, a=9.983(4), b=9.492(23), c=14.111(10) Angstroem, β=114.02(4) deg, and Z=2>.Splitting of the (1)H n.m.r. signal corresponding to the CH3C=group is attributed to the presence of two slowly interconverting rotamers (probably about the Pd-N bond), while a more rapid fluxional mode must be responsible for the temperature variation in the chemical shift of the CH2O groups.
