112126-70-2Relevant academic research and scientific papers
Umpolung of tropone: Preparation of 2-aroyl- and 2-acyltropones
Horikoshi, Hiroshi,Miyano, Hiroyuki,Takayasu, Tohru,Nitta, Makoto
, p. 4367 - 4373 (1999)
The reaction of 2-chlorotropone with DIBAH followed by aldolization with several aldehydes affords 2-(1-hydroxyalkyl)tropones, subsequent oxidation of which results in the formation of 2-aroyl- and 2-acyltropones.
Novel Base-Promoted Rearrangement of 2-(4-Cyano-, 2-Nitro-, and 4-Nitrobenzoyloxy)tropones and 2-(2-Oxo-2-phenethyloxy)tropone to 2--tropones and 2-(1-Hydroxy-2-oxo-2-phenethyl)tropone
Takeshita, Hitoshi,Mori, Akira,Suizu, Hiroshi
, p. 1429 - 1432 (2007/10/02)
The base-catalyzed rearrangement of 2-(2-nitro-, 4-nitro-, and 4-cyanobenzyloxy)tropones smoothly yielded corresponding 2-tropones, while their thermolysis gave 3-(arylmethyl)tropolones.This reaction has no precedent analogy in tropon
