Umpolung of tropone: Preparation of 2-aroyl- and 2-acyltropones

Article abstract of DOI:10.1080/00397919908086599

The reaction of 2-chlorotropone with DIBAH followed by aldolization with several aldehydes affords 2-(1-hydroxyalkyl)tropones, subsequent oxidation of which results in the formation of 2-aroyl- and 2-acyltropones.

Full text of DOI:10.1080/00397919908086599

Synthetic Communications
ISSN: 0039-7911 (Print) 1532-2432 (Online) Journal homepage: http://www.tandfonline.com/loi/lsyc20
Umpolung of Tropone: Preparation of 2-Aroyl- and
2-Acyltropones
Hiroshi Horikoshi , Hiroyuki Miyano , Tohru Takayasu & Makoto Nitta
To cite this article: Hiroshi Horikoshi , Hiroyuki Miyano , Tohru Takayasu & Makoto Nitta (1999)
Umpolung of Tropone: Preparation of 2-Aroyl- and 2-Acyltropones, Synthetic Communications,
29:24, 4367-4373, DOI: 10.1080/00397919908086599
To link to this article: http://dx.doi.org/10.1080/00397919908086599
Published online: 25 Sep 2007.
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Date: 10 June 2016, At: 20:23