112137-88-9

Upstream product

• 14516-54-2 bromopentacarbonylmanganese(I) 
• 17154-34-6 (trimethylsilyl)diphenylphosphine 
• 1643-19-2 tetrabutylammomium bromide 
• 829-85-6 diphenylphosphane 

Downstream Products

• 111800-45-4 potassium {tetracarbonyl(diphenylphosphine)manganate^(1-)} 
• 38148-37-7 MnBr(CO)3(PH(C₆H₅)2)2 
• 38148-37-7 MnBr(CO)3(PH(C₆H₅)2)2 

Relevant academic research and scientific papers

Preparation and Properties of, and Reactions with, Metal-Containing Heterocycles, XXIX. A Novel Phosphidomanganate as Starting Material for the Preparation of Phosphamanganacyclopropanes

The bifunctional phosphidomanganate 2- (2) is obtained by a two step reduction of (OC)4BrMnPPh2H (1) with sodium in THF.The presence of two adjacent nucleophilic centres in 2 is proved by the reaction with (CH3O)2SO2 and Br3Br, which results in the formation of (OC)4CH3MnPPh2CH3 (3) and (4), respectively.From 2 and Cl2CHR the manganacyclopropane derivatives (5a,b) with unusual bonding properties are obtained.According to an X-ray structural analysis, crystals of 5a are monoclinic, space groupP21/c with Z = 4.