112146-24-4Relevant academic research and scientific papers
Stereochemistry of sulfur-lithium and tin-lithium exchange reactions of functionalized cyclopropanes
Tanaka, Kazuhiko,Minami, Keizaburo,Funaki, Ikuo,Suzuki, Hitomi
, p. 2727 - 2730 (2007/10/02)
Sulfur-lithium exchange reaction of 2-substituted-2-(phenylthio)cyclopropanecarboxamides by LDMAN in THF at -50°C proceeded with invertion of configuration, leading to the predominant formation of trans-2-substituted cyclopropanes, while in tin-lithium ex
A Short, Efficient, Stereoselective Synthesis of Functionalized Cyclopropanes through the Cyclization of N-Phenyl-3-phenylthio-2-(phenylthiomethyl)propanamide
Tanaka, Kazuhiko,Minami, Keizaburo,Kaji, Aritsune
, p. 809 - 810 (2007/10/02)
Treatment of N-phenyl-3-phenylthio-2-(phenylthiomethyl)propanamide with 3.3 equiv. of butyllithium in THF-TMEDA produced a new dianion of 2-(phenylthio)cyclopropanecarboxamide which could react with a variety of electrophiles to give cyclopropanes with hi
