112150-19-3

Basic information

• Product Name: (±)-(1S,2S)-4'-methoxy-2,4,5-trimethyl-1,2,3,6-tetrahydro-1,1'-biphenyl
• Synonyms: (±)-(1S,2S)-4'-methoxy-2,4,5-trimethyl-1,2,3,6-tetrahydro-1,1'-biphenyl
• CAS NO: 112150-19-3
• Molecular Weight: 230.35
• Mol File: 112150-19-3.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: (±)-(1S,2S)-4'-methoxy-2,4,5-trimethyl-1,2,3,6-tetrahydro-1,1'-biphenyl(CAS DataBase Reference)
• NIST Chemistry Reference: (±)-(1S,2S)-4'-methoxy-2,4,5-trimethyl-1,2,3,6-tetrahydro-1,1'-biphenyl(112150-19-3)
• EPA Substance Registry System: (±)-(1S,2S)-4'-methoxy-2,4,5-trimethyl-1,2,3,6-tetrahydro-1,1'-biphenyl(112150-19-3)

Safety Data

• Hazardous Substances Data: 112150-19-3(Hazardous Substances Data)

Upstream product

• 513-81-5 2,3-dimethyl-buta-1,3-diene 
• 104-46-1 anethole 
• 123-11-5 4-methoxy-benzaldehyde 
• 4180-23-8 E-1-(4'-methoxyphenyl)prop-1-ene 

Relevant articles and documents

Green-light-driven thioxanthylium-based organophotoredox catalysts: Organophotoredox promoted radical cation Diels-Alder reaction

Thioxanthylium-based organophotoredox catalysts that operate under irradiation with green light have been developed. These catalysts present high excited-state reduction potentials (E0′(C?/C?) = +1.79–1.94 V vs SCE). They

Radical Cation Diels-Alder Reactions by TiO2 Photocatalysis

Radical cation Diels-Alder reactions by titanium dioxide (TiO2) photocatalysis in lithium perchlorate/nitromethane solution are described. TiO2 photocatalysis promotes reactions between electron-rich dienes and dienophiles, which would otherwise be difficult to accomplish due to electronic mismatching. The reactions are triggered by hole oxidation of the dienophile and are completed by the excited electron reduction of the radical cation intermediate at the dispersed surface in the absence of any sacrificial substrate.

Electronically Mismatched Cycloaddition Reactions via First-Row Transition Metal, Iron(III)-Polypyridyl Complex

The iron(III)-polypyridyl complex and its derivatives showed sufficient oxidizing potential to act as a one-electron oxidant, producing radical cations from olefins and promoting the efficient radical cation [2 + 2] and [2 + 4] cycloaddition reactions. Subsequent chain propagation afforded trisubstituted cyclobutane or cyclohexene derivatives, and this facile route enables the replacement of rare metals with sustainable, green, and inexpensive iron in radical cation cycloadditions.