112150-19-3

Upstream product

• 513-81-5 2,3-dimethyl-buta-1,3-diene 
• 4180-23-8 E-1-(4'-methoxyphenyl)prop-1-ene 
• 104-46-1 anethole 
• 123-11-5 4-methoxy-benzaldehyde 

Relevant academic research and scientific papers

Green-light-driven thioxanthylium-based organophotoredox catalysts: Organophotoredox promoted radical cation Diels-Alder reaction

Thioxanthylium-based organophotoredox catalysts that operate under irradiation with green light have been developed. These catalysts present high excited-state reduction potentials (E0′(C?/C?) = +1.79–1.94 V vs SCE). They

Structure and Reactivity of Aromatic Radical Cations Generated by FeCl3

This paper describes the isolation and characterization of an aromatic radical cation generated by FeCl3. X-ray crystallographic analysis and kinetic studies reveal the mechanism of the generation of aromatic radical cation. In the solid state,

Radical Cation Diels-Alder Reactions by TiO2 Photocatalysis

Radical cation Diels-Alder reactions by titanium dioxide (TiO2) photocatalysis in lithium perchlorate/nitromethane solution are described. TiO2 photocatalysis promotes reactions between electron-rich dienes and dienophiles, which would otherwise be difficult to accomplish due to electronic mismatching. The reactions are triggered by hole oxidation of the dienophile and are completed by the excited electron reduction of the radical cation intermediate at the dispersed surface in the absence of any sacrificial substrate.

Benign catalysis with iron: Facile assembly of cyclobutanes and cyclohexenes: Via intermolecular radical cation cycloadditions

We describe novel and facile iron-catalyzed crossed intermolecular radical cation cycloadditions of styrenes. This catalysis features high efficiency, atom economy, stereospecificity, scalability and very mild reaction conditions. Thus, these reactions re

Electronically Mismatched Cycloaddition Reactions via First-Row Transition Metal, Iron(III)-Polypyridyl Complex

The iron(III)-polypyridyl complex and its derivatives showed sufficient oxidizing potential to act as a one-electron oxidant, producing radical cations from olefins and promoting the efficient radical cation [2 + 2] and [2 + 4] cycloaddition reactions. Subsequent chain propagation afforded trisubstituted cyclobutane or cyclohexene derivatives, and this facile route enables the replacement of rare metals with sustainable, green, and inexpensive iron in radical cation cycloadditions.

Photocatalytic Cycloadditions Enabled by a Lithium Perchlorate/Nitromethane Electrolyte Solution

Photocatalytic cycloadditions involving carbon–carbon bond formation in the absence of an external sensitizer are described. The use of a lithium perchlorate/nitromethane electrolyte solution exhibiting remarkable Lewis acidity is the key for the successf

Visible-Light-Irradiated Graphitic Carbon Nitride Photocatalyzed Diels–Alder Reactions with Dioxygen as Sustainable Mediator for Photoinduced Electrons

Photocatalytic Diels–Alder (D–A) reactions with electron rich olefins are realized by graphitic carbon nitride (g-C3N4) under visible-light irradiation and aerobic conditions. This heterogeneous photoredox reaction system is highly e

Photoassisted oxidation of ruthenium(ii)-photocatalysts Ru(bpy)32+ and Ru(bpz)32+ to RuO4: Orthogonal tandem photoredox and oxidation catalysis

Common photoredox catalysts Ru(bpy)32+ and Ru(bpz)32+ are rapidly converted into Ruthenium(viii)-oxide through continuous visible light irradiation in the presence of NaIO4 or H5IO6/s

Aromatic "redox Tag"-assisted Diels-Alder reactions by electrocatalysis

Electrocatalysis was employed to promote Diels-Alder reactions between electronically mismatched substrates. A catalytic amount of electricity was enough to complete the overall reactions and GC-MS monitoring and CV measurements clearly illustrated the el