112166-48-0Relevant academic research and scientific papers
Effect of Through-Bond Interaction on Conformation and Structure of Some N-Arylpiperidone and N-Aryltropanone Derivatives.
Krijnen, B.,Beverloo, H. B.,Verhoeven, J. W.,Reiss, C. A.,Goubitz, K.,Heijdenrijk, D.
, p. 4433 - 4440 (1989)
Through-bond interaction (TBI) in N-aryl-4-piperidone derivatives in which the carbonyl group is modified to enhance its electron deficiency is found to stabilize the sterically disfavored axial arrangement of the aryl group, an arrangement also found in
