Journal of the American Chemical Society p. 4433 - 4440 (1989)
Update date:2022-09-26
Topics: Steric Effects Conformational Changes Influence on Reactivity
Krijnen, B.
Beverloo, H. B.
Verhoeven, J. W.
Reiss, C. A.
Goubitz, K.
Heijdenrijk, D.
Through-bond interaction (TBI) in N-aryl-4-piperidone derivatives in which the carbonyl group is modified to enhance its electron deficiency is found to stabilize the sterically disfavored axial arrangement of the aryl group, an arrangement also found in
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