1122-85-6

Basic information

• Product Name: phenyl cyanate
• Synonyms: Cyanic acid phenyl ester solution;Phenyl cyanate solution;Phenyl cyanate solution ~20 wt. % in dichloromethane, >=90% (GC);cyanatobenzene;Cyanic Acid Phenyl Ester;Phenoxy cyanide;Cyanatobenzene solution
• CAS NO: 1122-85-6
• Molecular Formula: C₇H₅NO
• Molecular Weight: 119.1207
• EINECS: 214-364-5
• Product Categories: Aromatics Compounds;Aromatics
• Mol File: 1122-85-6.mol
• Article Data: 21

Chemical Properties

• Melting Point: 45-50°C
• Boiling Point: 77-79°C @13mm
• Flash Point: 62.7°C
• Appearance: /
• Density: ~1.27 g/mL at 20 °C
• Vapor Pressure: 1.68mmHg at 25°C
• Refractive Index: 1.527
• Storage Temp.: -20°C Freezer
• BRN: 507925
• CAS DataBase Reference: phenyl cyanate(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl cyanate(1122-85-6)
• EPA Substance Registry System: phenyl cyanate(1122-85-6)

Safety Data

• Hazard Codes: Xn
• Statements: 40-42/43
• Safety Statements: 23-36/37-45
• RIDADR: UN 1593 6.1 / PGIII
• WGK Germany: 3
• Hazardous Substances Data: 1122-85-6(Hazardous Substances Data)

Usage

Chemical Properties

Light Pink Oil

InChI:InChI=1/C7H5NO/c8-6-9-7-4-2-1-3-5-7/h1-5H

Upstream product

• 70989-49-0 2-thioxo-benzooxazole-3-carboximidic acid phenyl ester 
• 506-68-3 bromocyane 
• 108-95-2 phenol 
• 1483-72-3 diphenyliodonium chloride 
• 859214-48-5 2-cyano-4,5-dichloropyridazin-3(2H)-one 
• 582-61-6 benzoyl azide 
• 76347-03-0 3-methyl-4-(O-phenyloximino)isoxazol-5(4H)-one 
• 90368-32-4 2,2-dimethyl-1,3-dioxane-4,5,6-trione O-phenyloxime 

Downstream Products

• 704-56-3 2-amino-5-(pyridin-4-yl)-1,3,4-oxadiazole 
• 3190-43-0 Semicarbazid-1,1-bis- 
• 1850-14-2 tetramethoxymethane 
• 40588-57-6 Kohlensaeurephenylester-methylester-imid 
• 1102-40-5 C₂₀H₂₆N₄O₂ 
• 25344-34-7 Phenyl N-(chlorocarbonyl)-1-chlorocarbonimidate 
• 25344-41-6 {[1-Chloro-1-phenoxy-meth-(Z)-ylidene]-amino}-oxo-acetyl chloride 
• 25344-38-1 N,N'-Bis-[1-chloro-1-phenoxy-meth-(Z)-ylidene]-oxalamide 
• 34197-71-2 Phenyl N-(benzhydryl)carbamate 
• 54561-81-8 3-Phenyl-carbimidoyl-methylcarbazat 
• 78-09-1 orthocarbonic acid tetraethyl ester 
• 53656-57-8 1,2-Dimethyl-2-phenylcarbimidoylhydrazin 
• 120-65-0 ortho-dimethylaminomethylphenol 
• 20494-36-4 1-cyano-3-ethyl-2-phenylisourea 

Related news

A comparison of the surface chemistry of phenyl cyanate (cas 1122-85-6) and phenol on Al(111)09/24/2019

The surface chemistry of phenyl cyanate and phenol on Al(111) was investigated by temperature-programmed desorption and X-ray photoelectron spectroscopy between 100 and 800 K. Chemisorption of the initial monolayer occurred via cleavage of the OCN bond for phenyl cyanate and the OH bond for ...detailed

Relevant articles and documents

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Highly Enantioselective α-Cyanation with 4-Acetylphenyl Cyanate

A highly effective asymmetric version of α-cyanation of β-keto esters and amides was developed with a Lewis-acid catalyst. Thus, by using 10 mol % of a tridentate bisoxazoline–zinc(II) complex as the catalyst, a series of chiral nitriles containing a quaternary carbon center were obtained in excellent enantioselectivities (up to 97 % enantiomeric excess) and up to 95 % yield in the presence of 4 ? molar sieve at room temperature. For the first time, mild and active 4-acetylphenyl cyanate was used instead of cyano-hyperiodinate as the cationic cyano source for catalytic asymmetric α-cyanation.

Oxidative rearrangement strategy for synthesis of 2,4,5-trisubstituted oxazoles utilizing hypervalent iodine reagent

Hypervalent iodine (III)-intermediated direct oxidative rearrangement of 3-hydroxybut-2-enimidates affording oxazoles under mild conditions has been developed. This protocol provides a new methodology to the synthesis of compounds containing oxazole structure.