112222-09-0

Basic information

• Product Name: 2-tert-Butyl-3,3-dimethyl-N-(phenylsulfonyl)butyramid
• Synonyms: 2-tert-Butyl-3,3-dimethyl-N-(phenylsulfonyl)butyramid
• CAS NO: 112222-09-0
• Molecular Weight: 311.445
• Mol File: 112222-09-0.mol

Chemical Properties

• CAS DataBase Reference: 2-tert-Butyl-3,3-dimethyl-N-(phenylsulfonyl)butyramid(CAS DataBase Reference)
• NIST Chemistry Reference: 2-tert-Butyl-3,3-dimethyl-N-(phenylsulfonyl)butyramid(112222-09-0)
• EPA Substance Registry System: 2-tert-Butyl-3,3-dimethyl-N-(phenylsulfonyl)butyramid(112222-09-0)

Safety Data

• Hazardous Substances Data: 112222-09-0(Hazardous Substances Data)

Upstream product

• 16797-75-4 di-tert-butylthioketene 
• 2845-62-7 benzenesulphonyl isocyanate 

Relevant articles and documents

Cycloaddition Reactions of Heterocumulenes, XXIX. - Reactions of Thioketenes with Isocyanates

The cycloaddition of thioketenes 1a-f to isocyanates 2a-f yields 4-thioxo-2-azetidinones 3 as main products, which may isomerize to 4-imino-2-thietanones 5.In competing reactions, 2,4-azetidinediones 8, N-sulfonylamides 9, and 3H-1,2,4-dithiazoles 15 are formed.Thioketenes 1 react with chlorosulfonyl isocyanate (20b) to give N-unsubstituted 4-thioxo-2-azetidinones 22.Depending on the thioketene 1 and the reaction conditions, compounds 23-26 also result.The consitutions of 15b and 23a were determined by X-ray structural analyses.