112222-87-4Relevant academic research and scientific papers
'Green' methodology for efficient and selective benzoylation of nucleosides using benzoyl cyanide in an ionic liquid
Prasad, Ashok K.,Kumar, Vineet,Malhotra, Shashwat,Ravikumar, Vasulinga T.,Sanghvi, Yogesh S.,Parmar, Virinder S.
, p. 4467 - 4472 (2005)
Benzoyl cyanide in the ionic liquid 1-methoxyethyl-3-methylimidazolium methanesulfonate has been employed as a 'green' alternative and mild reaction condition protocol to conventional pyridine-benzoyl chloride system for efficient and selective benzoylation of nucleosides (of both the ribo- and deoxyribo-series) at ambient temperatures. The use of benzoyl cyanide-ionic liquid combination has been successfully extended for highly efficient benzoylation of phenols, aromatic amines, benzyl alcohol, aliphatic diols, 3-aminophenol and 2-aminobenzylalcohol, which indicates the versatility of this benzoylating system.
Polymorphic diversity: N-phenylbenzamide as a possible polymorphophore
Zipp, Caitlin F.,Dirr, Heini W.,Fernandes, Manuel A.,Marques, Helder M.,Michael, Joseph P.
, p. 3463 - 3474 (2013/09/02)
In this work, we identify and describe a moiety that may be capable of encouraging the formation of polymorphs. Four new N-phenylbenzamide-based compounds have been synthesized yielding four pairs of polymorphs upon recrystallization. The structures of th
