112371-30-9Relevant academic research and scientific papers
ELECTROCHEMICAL OXIDATION OF 1-TRIMETHYLSILYL-1,3-DIENES
Yoshida, Jun-ichi,Murata, Toshiki,Isoe, Sachihiko
, p. 211 - 214 (2007/10/02)
Electrochemical oxidation of 1-trimethylsilyl-1,3-dienes in methanol afforded 1,1,4-trimethoxy-2-butene derivatives, which were readily hydrolyzed to the corresponding α,β-unsaturated aldehydes.By combination of this electrochemical reaction with the synthesis of 1-trimethylsilyl-1,3-dienes from carbonyl compounds, 1,3-bis(trimethylsilyl)propene provides a β-formylvinyl anion equivalent.
