1123885-72-2Relevant academic research and scientific papers
Synthesis of Functionalized Benzo[g]indoles and 1-Naphthols via Carbon-Carbon Triple Bond Breaking/Rearranging
Wang, Jia-Yin,Zhou, Peng,Li, Guigen,Hao, Wen-Juan,Tu, Shu-Jiang,Jiang, Bo
, p. 6682 - 6685 (2017)
Novel carbon-carbon triple bond breaking and rearranging reactions of benzene-linked allene-ynes have been established. The reactions can be selectively controlled toward the formation of two families of skeletally diverse benzo[g]indoles and 1-naphthols
Synthesis of Functionalized Cyclobutane-Fused Naphthalene Derivatives via Cascade Reactions of Allenynes with tert-Butyl Nitrite
Feng, Tian,He, Yan,Zhang, Xinying,Fan, Xuesen
, (2019/02/07)
A novel synthesis of cyclobutanol-fused 2-nitronaphthalen-1-ols and nitrocyclobutane-fused naphthalene-1,2-diones through cascade reactions of benzene-linked allenynes with tert-butyl nitrite is presented. The formation of the title compounds involves a tandem process including allenyne [2+2] cycloaddition, radical addition onto the in situ formed cyclobutenyl moiety followed by radical coupling/oxidation. Interestingly, different kinds of functionalized naphthalene derivatives could be obtained selectively from the same substrates, and the selectivity was easily controlled by finely tuning the reaction conditions. (Figure presented.).
Novel platinum-catalyzed tandem reaction: An efficient approach to construct naphtho[l,2-b]furan
Wei, Hao,Zhai, Hongbin,Xu, Peng-Fei
supporting information; experimental part, p. 2224 - 2226 (2009/07/01)
An efficient approach to synthesize naphtho[1,2-b]furan has been developed via platinum-catalyzed tandem reaction. This new tandem catalysis induces a cycloisomerization of allenyl ketone, followed by a 6Π-electrocyclization- type reaction of carbene intermediate. The metal carbene proved to be an effective intermediate in the 6π-electrocyclization-type reaction.
