112425-49-7Relevant academic research and scientific papers
REACTIONS OF α,β-UNSATURATED KETONES WITH ARYLACETONITRILES
Al-Arab, Mohammad M.,Issa, Ali M.
, p. 1021 - 1025 (2007/10/02)
1,3-Diaryl-2-propene-1-ones I react with arylacetonitriles II in the presence of sodium ethoxide at room temperature to give a single diastereomer of the corresponding 2,3-diaryl-4-aroylbutyronitriles III.The structures of the reaction products were estab
Cyclic voltammetry study of the non-aqueous electrochemical oxidation of aromatic cyanoesters and cyanoketones
Al-Arab, Mohammad M.,Barqawi, Khaled R.,Tabba, Hani D.
, p. 787 - 790 (2007/10/02)
With cyclic voltammetry, anodic oxidation potentials for a series of 36 substituted aromatic cyanoesters and cyanoketones have been measured and analyzed.The different aromatic moieties showed different potential values in accordance with the substituent type and nature of aromatic nucleus.The voltammograms indicate irreversible anodic oxidation of the aromatic substrate upon scanning from -2.40 to +2.90 volts versus SCE.Compounds comprising two or more aryl groups having oxidation potential difference of 0.30 V or more, show voltammogram with two oxidation waves.
