Cas 112449-74-8,tert-Butyl-((E)-(2S,3R)-2,4-dimethyl-3-phenylsulfanyl-hex-4-enyloxy)-diphenyl-silane

112449-74-8

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Basic information

Product Name: tert-Butyl-((E)-(2S,3R)-2,4-dimethyl-3-phenylsulfanyl-hex-4-enyloxy)-diphenyl-silane
Synonyms:
CAS NO:112449-74-8
Molecular Formula:
Molecular Weight: 474.783
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: tert-Butyl-((E)-(2S,3R)-2,4-dimethyl-3-phenylsulfanyl-hex-4-enyloxy)-diphenyl-silane(CAS DataBase Reference)
NIST Chemistry Reference: tert-Butyl-((E)-(2S,3R)-2,4-dimethyl-3-phenylsulfanyl-hex-4-enyloxy)-diphenyl-silane(112449-74-8)
EPA Substance Registry System: tert-Butyl-((E)-(2S,3R)-2,4-dimethyl-3-phenylsulfanyl-hex-4-enyloxy)-diphenyl-silane(112449-74-8)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 112449-74-8(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 112449-74-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,2,4,4 and 9 respectively; the second part has 2 digits, 7 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 112449-74:
(8*1)+(7*1)+(6*2)+(5*4)+(4*4)+(3*9)+(2*7)+(1*4)=108
108 % 10 = 8
So 112449-74-8 is a valid CAS Registry Number.

112449-74-8Upstream product

112449-94-2 (2S,3R,4S)-1-(tert-Butyl-diphenyl-silanyloxy)-2,4-dimethyl-4-phenylsulfanyl-hexan-3-ol

112449-74-8Downstream Products

112449-74-8Relevant academic research and scientific papers

SYNTHESIS OF COMMPOUNDS WITH 1,4-RELATED CHIRAL CENTRES BY PHENYLTHIO MIGRATION: SYN AND ANTI-E-2,4-DIMETHYLHEX-3-ENE-1,5-DIOL

Aggarwal, Varinder K.,Warren, Stuart

, p. 1925 - 1928 (1987)

The aldol product from an α-PhS aldehyde, formed with high Cram and anti (aldol) selectivity, was transformed by PhS migration into the syn title compound: the anti compound was made by a Claisen-Ireland rearrangement.

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