112449-94-2

Upstream product

• 112449-95-3 (2RS,3RS,4RS)-2,6-Dimethylphenyl 2,4-dimethyl-3-hydroxy-4-phenylsulfanylhexanoate 
• 98793-42-1 2-methyl-2-(phenylsulfenyl)butanal 
• 112449-84-0 (2RS,3SR,4SR)-2,4-Dimethyl-3-hydroxy-4-phenylsulfanylhexane-1,3-diol 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 112449-90-8 tert-Butyl-((2S,3S)-2-methyl-4-methylene-3-phenylsulfanyl-hexyloxy)-diphenyl-silane 
• 112449-74-8 tert-Butyl-((E)-(2S,3R)-2,4-dimethyl-3-phenylsulfanyl-hex-4-enyloxy)-diphenyl-silane 
• 112449-92-0 (E)-(2S,5R)-6-(tert-Butyl-diphenyl-silanyloxy)-3,5-dimethyl-hex-3-en-2-ol 

Relevant academic research and scientific papers

SYNTHESIS OF COMMPOUNDS WITH 1,4-RELATED CHIRAL CENTRES BY PHENYLTHIO MIGRATION: SYN AND ANTI-E-2,4-DIMETHYLHEX-3-ENE-1,5-DIOL

The aldol product from an α-PhS aldehyde, formed with high Cram and anti (aldol) selectivity, was transformed by PhS migration into the syn title compound: the anti compound was made by a Claisen-Ireland rearrangement.