112449-86-2

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 112449-87-3 Propionic acid (E)-1,2-dimethyl-3-phenylsulfanyl-allyl ester 
• 34884-33-8 (phenylthio)-methylenetriphenylphosphorane 
• 112449-89-5 (E)-3-methyl-4-phenylsulfinyl-3-buten-2-one 
• 112449-88-4 3-Methyl-4-phenylsulfanylbut-3-en-2-ol 

Downstream Products

• 112449-82-8 (E)-(2S,3R)-2,4-Dimethyl-3-phenylsulfanyl-hex-4-enoic acid 
• 112449-82-8 (E)-(2R,3R)-2,4-Dimethyl-3-phenylsulfanyl-hex-4-enoic acid 
• 112449-78-2 (E)-(2S,3S)-2,4-Dimethyl-3-phenylsulfanyl-hex-4-en-1-ol 

Relevant academic research and scientific papers

SYNTHESIS OF COMMPOUNDS WITH 1,4-RELATED CHIRAL CENTRES BY PHENYLTHIO MIGRATION: SYN AND ANTI-E-2,4-DIMETHYLHEX-3-ENE-1,5-DIOL

The aldol product from an α-PhS aldehyde, formed with high Cram and anti (aldol) selectivity, was transformed by PhS migration into the syn title compound: the anti compound was made by a Claisen-Ireland rearrangement.