112474-95-0Relevant academic research and scientific papers
Directing Effects of a Silyl Group on Cationic Rearrangement Reactions
Tanino, Keiji,Hatanaka, Yasuo,Kuwajima, Isao
, p. 385 - 388 (1987)
In the reaction of 3-(trimethylsilyl)methylcyclohexyl mesylates with dimethylaluminum triflate, the silyl group has a remarkable effect to induce successive rearrangements of a hydride and an alkyl group so as to form a stable β-silyl cationic species whi
