Directing Effects of a Silyl Group on Cationic Rearrangement Reactions

DOI: 10.1246/cl.1987.385

Source and publish data:

Chemistry Letters p. 385 - 388 (1987)

Update date:2022-08-16

Topics:

Authors:

Tanino, Keiji

Hatanaka, Yasuo

Kuwajima, Isao

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1987.385

In the reaction of 3-(trimethylsilyl)methylcyclohexyl mesylates with dimethylaluminum triflate, the silyl group has a remarkable effect to induce successive rearrangements of a hydride and an alkyl group so as to form a stable β-silyl cationic species whi

Full text of DOI:10.1246/cl.1987.385

Products guided by the article

Product name:Cyclopentane, 1-methyl-1-(1-methylenepentyl)-

Cas No:112474-95-0

R&D Labs maybe for 112474-95-0

zhenjiang runjing high purity chemical co ltd

Contact:+86-511-83361155

Address:No.8.haixi road,international chemical park
Meryer (Shanghai) Chemical Technology Co., Ltd.

website:http://www.meryer.com/cn/index/

Contact:+86-755-86170518

Address:Minhang,Shanghai, China
XI'AN CHUKANG BIOTECHNOLOGY CO.,LTD

Contact:29-63685658 63685359

Address:Room 3-1202,Building 1,Oriental oasis,East of Xianning Road,Xi'an,Shaanxi 710043 P.R.China
Hangzhou utanpharma Co., Ltd

Contact:86-571-87758773

Address:Room604 ,6F, Block A1-3 Xixi Plaza,No. 588 Wenyi West RD, Hangzhou,310012, China
Nanjing Capatue Chemical Co., Ltd

Contact:+86-25-86371192 +86-025-85720158

Address:No.20 Jiangjun Avenue, Jiangning Economic & Technical Development Zone

Relevant to this article

Doi:10.1021/jo01080a006
(1960)
Doi:10.1002/hlca.19500330312
(1950)
Rhodium-catalyzed direct alkenylation and arylation of arene C-H bonds via decarbonylation of cinnamoyl chlorides, cinnamic anhydrides, and poly(aroyl) chlorides

Doi:10.1021/om900997y
(2010)
Dual emission from (E)-3-(4-methylamino-phenyl)-acrylic acid ethyl ester (MAPAEE) and its application as fluorescence probe for studying micellar and protein microenvironment

Doi:10.1016/j.molstruc.2008.07.007
(2009)
Selective formation of formamidines, carbodiimides and formimidates from isocyanide complexes of Mn(i) mediated by Ag₂O

Doi:10.1039/c8dt01200h
(2018)
Doi:10.1021/ja01313a031
(1935)

Article Doi