Directing Effects of a Silyl Group on Cationic Rearrangement Reactions

DOI: 10.1246/cl.1987.385

Source and publish data:

Chemistry Letters p. 385 - 388 (1987)

Update date:2022-08-16

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Authors:

Tanino, Keiji

Hatanaka, Yasuo

Kuwajima, Isao

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Article abstract of DOI:10.1246/cl.1987.385

In the reaction of 3-(trimethylsilyl)methylcyclohexyl mesylates with dimethylaluminum triflate, the silyl group has a remarkable effect to induce successive rearrangements of a hydride and an alkyl group so as to form a stable β-silyl cationic species whi

Full text of DOI:10.1246/cl.1987.385

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