112476-27-4

Basic information

• Product Name: 1-Pyrrolidinecarboxylic acid, 4-methyl-2-[(phenyltelluro)methyl]-, ethyl ester
• CAS NO: 112476-27-4
• Molecular Formula: C15H21NO2Te
• Molecular Weight: 374.937
• Mol File: 112476-27-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-Pyrrolidinecarboxylic acid, 4-methyl-2-[(phenyltelluro)methyl]-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Pyrrolidinecarboxylic acid, 4-methyl-2-[(phenyltelluro)methyl]-, ethyl ester(112476-27-4)
• EPA Substance Registry System: 1-Pyrrolidinecarboxylic acid, 4-methyl-2-[(phenyltelluro)methyl]-, ethyl ester(112476-27-4)

Safety Data

• Hazardous Substances Data: 112476-27-4(Hazardous Substances Data)

Upstream product

• 112476-37-6 benzenetellurinyl trifluoroacetate 
• 112476-23-0 (2-Methyl-pent-4-enyl)-carbamic acid ethyl ester 
• 94971-86-5 benzenetellurinic acid anhydride 

Relevant articles and documents

Aminotellurinylation of Olefins and Its Utilization for Synthesis of 2-Oxazolidinones

Benzenetellurinyl acetate or trifluoroacetate in combination with ethyl carbamate effected regio- and stereoselective aminotellurinylation of olefins in the presence of boron trifluoride etherate in chloroform under reflux to give ethyl carbamates in high yields.Benzenetellurinyl trifluoromethanesulfonate similarly did it even at the lower temperature of refluxing dichloromethane without Lewis acid.This reaction was successfully extended to cyclofunctionalization of olefinic carbamates into nitrogen heterocycles.Furthermore, when the aminotellurinylation was carried out in refluxing 1,2-dichloroethane, 2-oxazolidinone was obtained in a high yield.A mechanism of addition followed by intramolecular substitution in proposed on the basis of the stereochemistry of 2-oxazolidinone derivatives.