112483-13-3

Upstream product

• 151-50-8 potassium cyanide 
• 112482-94-7 benzyl 3,4-anhydro-α-D-ribopyranoside 
• 112482-93-6 benzyl 3,4-dideoxy-α-D-glycero-pent-3-enopyranoside 
• 112348-34-2 benzyl 4-bromo-4-deoxy-2-O-benzoyl-β-L-lyxopyranoside 
• 112348-33-1 benzyl 2-O-benzoyl-α-D-erythro-pent-3-enopyranoside 
• 112348-36-4 benzyl 4-bromo-4-deoxy-β-L-lyxopyranoside 
• 18403-20-8 benzyl 2-O-benzoyl-α-D-xylopyranoside 
• 7677-24-9 trimethylsilyl cyanide 
• 61134-24-5 Benzyl 2,3-anhydro-α-D-ribopyranoside 

Downstream Products

• 112482-99-2 benzyl 3-cyano-3-deoxy-2,4-di-O-benzoyl-α-D-xylopyranoside 

Relevant academic research and scientific papers

A Regioselective One Pot Synthesis and Synthetic Applications of Cyanodeoxy Sugars by Cyanotrimethylsilane

The regioselective epoxide opening of different 2,3-anhydropyranoses by cyanotrimethylsilane is investigated.The isolated cyanodeoxy pyranoses allow easy access to the corresponding branched-chains aminomethyl sugars by lithium aluminium hydride reduction

Regiospecific Ring-Opening Reactions of Benzyl 3,4-Anhydro-α-D-ribopyranoside with Nucleophiles: A Systematic Study

Nucleophilic ring-opening reactions of the title compound 6 and its (benzyloxy)methyl ether 27 with different nucleophiles resulted in exclusive formation of 3-substituted 3-deoxyxylose derivatives.On the basis of these experiments, it is postulated that

REGIOSELECTIVE ONE POT SYNTHESES OF CYANODEOXY SUGARS

A rapid high yielding regioselective approach to cyanodeoxy sugars (5-8) has been developed by way of trans diaxial cleavage of the oxirane ring in 2,3-anhydro sugars (1-4) with cyanotrimethylsilane using aluminium chloride as catalyst.