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112518-17-9

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112518-17-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 112518-17-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,2,5,1 and 8 respectively; the second part has 2 digits, 1 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 112518-17:
(8*1)+(7*1)+(6*2)+(5*5)+(4*1)+(3*8)+(2*1)+(1*7)=89
89 % 10 = 9
So 112518-17-9 is a valid CAS Registry Number.

112518-17-9Relevant articles and documents

Bronsted base-modulated regioselectivity in the aerobic oxidative amination of styrene catalyzed by palladium

Timokhin, Vitaliy I.,Stahl, Shannon S.

, p. 17888 - 17893 (2005)

Palladium(II)-catalyzed aerobic oxidative amination of styrene with oxazolidinone proceeds with catalyst-controlled regioselectivity: (CH 3CN)2PdCl2 (1) and (Et3N) 2PdCl2 (2) catalyze forma

Palladium(II)-Catalyzed Amidation of Alkenes

Hosokawa, Takahiro,Takano, Minoru,Kuroki, Yoshichika,Murahashi, Shun-Ichi

, p. 6643 - 6646 (1992)

PdCl2(MeCN)2 catalyzes amidation of electron-deficient alkenes leading to enamides, where cyclic carbamates are more reactive than cyclic amides as nucleophiles.

Ethanol as a Hydrogenating Agent: Palladium-Catalyzed Stereoselective Hydrogenation of Ynamides To Give Enamides

Siva Reddy, Alla,Kumara Swamy

supporting information, p. 6984 - 6988 (2017/06/06)

Ethanol is shown to act as a hydrogenating agent for ynamides under palladium catalysis. This behavior is different from the normally expected reaction of ethanol addition to alkynes. The reaction shows stereoselectivity for E enamides, which is in contrast to reports using other hydrogenating sources. The method was also extended to ynamines. Alternatively, the use of ethanol and ammonium formate as the hydrogenating source gives Z enamides. The role of ethanol in hydrogenation was demonstrated by means deuterium labeling experiment.

Direct C-H functionalization of enamides and enecarbamates by using visible-light photoredox catalysis

Jiang, Heng,Huang, Chengmei,Guo, Jiajia,Zeng, Chuanqi,Zhang, Yan,Yu, Shouyun

, p. 15158 - 15166 (2013/01/15)

Direct C-H functionalization of various enamides and enecarbamates was realized through visible-light photoredox catalyzed reactions. Under the optimized conditions using [Ir(ppy)2(dtbbpy)PF6] as photocatalyst in combination with Na

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