112518-17-9Relevant articles and documents
Bronsted base-modulated regioselectivity in the aerobic oxidative amination of styrene catalyzed by palladium
Timokhin, Vitaliy I.,Stahl, Shannon S.
, p. 17888 - 17893 (2005)
Palladium(II)-catalyzed aerobic oxidative amination of styrene with oxazolidinone proceeds with catalyst-controlled regioselectivity: (CH 3CN)2PdCl2 (1) and (Et3N) 2PdCl2 (2) catalyze forma
Palladium(II)-Catalyzed Amidation of Alkenes
Hosokawa, Takahiro,Takano, Minoru,Kuroki, Yoshichika,Murahashi, Shun-Ichi
, p. 6643 - 6646 (1992)
PdCl2(MeCN)2 catalyzes amidation of electron-deficient alkenes leading to enamides, where cyclic carbamates are more reactive than cyclic amides as nucleophiles.
Ethanol as a Hydrogenating Agent: Palladium-Catalyzed Stereoselective Hydrogenation of Ynamides To Give Enamides
Siva Reddy, Alla,Kumara Swamy
supporting information, p. 6984 - 6988 (2017/06/06)
Ethanol is shown to act as a hydrogenating agent for ynamides under palladium catalysis. This behavior is different from the normally expected reaction of ethanol addition to alkynes. The reaction shows stereoselectivity for E enamides, which is in contrast to reports using other hydrogenating sources. The method was also extended to ynamines. Alternatively, the use of ethanol and ammonium formate as the hydrogenating source gives Z enamides. The role of ethanol in hydrogenation was demonstrated by means deuterium labeling experiment.
Direct C-H functionalization of enamides and enecarbamates by using visible-light photoredox catalysis
Jiang, Heng,Huang, Chengmei,Guo, Jiajia,Zeng, Chuanqi,Zhang, Yan,Yu, Shouyun
, p. 15158 - 15166 (2013/01/15)
Direct C-H functionalization of various enamides and enecarbamates was realized through visible-light photoredox catalyzed reactions. Under the optimized conditions using [Ir(ppy)2(dtbbpy)PF6] as photocatalyst in combination with Na
