112529-04-1

Basic information

• Product Name: Benzene, 1,1'-[3-(2-propenyl)-1-propene-1,3-diyl]bis-
• CAS NO: 112529-04-1
• Molecular Formula: C18H18
• Molecular Weight: 234.341
• Mol File: 112529-04-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-[3-(2-propenyl)-1-propene-1,3-diyl]bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-[3-(2-propenyl)-1-propene-1,3-diyl]bis-(112529-04-1)
• EPA Substance Registry System: Benzene, 1,1'-[3-(2-propenyl)-1-propene-1,3-diyl]bis-(112529-04-1)

Safety Data

• Hazardous Substances Data: 112529-04-1(Hazardous Substances Data)

Upstream product

• 112528-84-4 2-((E)-1,3-Diphenyl-allyloxy)-tetrahydro-pyran 
• 762-72-1 allyl-trimethyl-silane 
• 4663-33-6 1,3-diphenyl-3-hydroxypropene 
• 86477-17-0 (3-methoxyprop-1-ene-1,3-diyl)dibenzene 

Relevant articles and documents

Iron-catalyzed π-activated C-O ether bond cleavage with C-C and C-H bond formation

A novel and efficient allylic alkylation reaction between π-activated ethers and allylsilane was realized under mild conditions through iron(III)-catalyzed C sp 3-O ether bond cleavage. The present protocol provides an attractive approach for the construction of sp3-sp3 C-C bonds and can be potentially applied for the selective reduction of benzyl and allyl ethers to their corresponding hydrocarbon compounds by using triethylsilane as a hydride-transfer reagent. A mild, economical, and environmentally friendly method for the construction of C sp 3-C sp 3 bonds through iron-catalyzed π-activated C-O ether bond cleavage is developed. In addition, this catalytic system can be used for the selective reduction of benzylic and allylic C-O ether bonds to C-H bonds. Copyright

Catalytic coupling of N-benzylic sulfonamides with silylated nucleophiles at room temperature

In the presence of 2-10 mol% of Tf2NH, a range of N-benzylic sulfonamides smoothly react with allylic, propargylic, benzylic, or hydrido silanes at room temperature via sp3 carbon-nitrogen bond cleavage to afford structurally diverse products in moderate to excellent yields and with high chemo- and regioselectivity.

Efficient and mild iron-catalyzed direct allylation of benzyl alcohols and benzyl halides with allyltrimethylsilane

An efficient and mild iron-catalyzed direct allylation of benzyl alcohols and benzyl halides with allyltrimethylsilane has been developed. The present reaction would provide an excellent alternative to published methods because of its excellent yields, sustainable catalyst, and mild conditions. Copyright Taylor & Francis Group, LLC.