112583-77-4

Upstream product

• 112583-78-5 1-dimethylamino-2,4-dibenzoyl-3-methylbutane 
• 1226-91-1 3-methyl-1,5-diphenyl-pentane-1,5-dione 

Downstream Products

• 112539-47-6 2-(3-oxo-1-methyl-3-phenylpropyl)-1-indanone 
• 131261-60-4 5-benzoyl-4-methyl-1,2-diphenylphosphorinane 1-oxide 
• 112583-80-9 1-Methyl-3-phenyl-4-azafluorene 
• 69751-55-9 4-methyl-2-phenyl-5H-indeno[1,2-b]pyridin-5-one 

Relevant academic research and scientific papers

REACTIONS OF 1,5-DIKETONES. XLIX. SYNTHESIS OF THE PHENYL ANALOG OF THE ALKALOID ONYCHINE

1-Methyl-3-phenyl-4-azafluorene was obtained by intramolecular cyclization of 2,4-dibenzoyl-3-methylbutene by the action of sulfuric acid followed by closure of the pyridine ring in the obtained 2-(3-oxo-1-methyl-3-phenylpropyl)-1-indanone by the action o

An Efficient and Convenient Method for the Preparation of α-Methylenated Ketones from Silyl Enol Ethers

In the presence of a catalytic amount of stannous halide, silyl enol ethers react with bromomethyl methyl ether to give the corresponding α-bromoethyl ketones, which are smoothly converted to α-methylenated ketones on the successive addition of tertiary amine by one-pot procedure.This method is successfully applied to a synthesis of sarkomycin intermediate.