112621-64-4Relevant articles and documents
Eu(fod)3-catalyzed rearrangement of allylic methoxyacetates
Shull, Brian K.,Sakai, Takashi,Koreeda, Masato
, p. 11690 - 11691 (2007/10/03)
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Enantioselective cyclizations of acyclic 1,5-diketones
Agami, Claude,Platzer, Nicole,Sevestre, Hubert
, p. 358 - 360 (2007/10/02)
4-Methyl-2,6-heptanedione 1 was cyclized to enone (-)-4 via a (S)-proline-catalyzed intramolecular aldol reaction followed by dehydration.Replacement of the 4-methyl group by either an iso-propyl or a tert-butyl subtituent leads to a dramatic lowering of