112654-23-6Relevant academic research and scientific papers
Carboallylation of Electron-Deficient Alkenes with Organoboron Compounds and Allylic Carbonates by Cooperative Palladium/Copper Catalysis
Semba, Kazuhiko,Ohta, Naoki,Nakao, Yoshiaki
, p. 4407 - 4410 (2019)
The aryl- and alkylallylation of electron-deficient alkenes was achieved by cooperative palladium/copper catalysis. The reaction affords various carbon skeletons from readily available alkenes, allylic carbonates, and organoboron compounds, whereby a vari
Carboallylation of electron-deficient alkenes by palladium/copper catalysis
Semba, Kazuhiko,Ohta, Naoki,Yano, Yuko,Nakao, Yoshiaki
supporting information, p. 11463 - 11466 (2018/10/20)
A method for the carboallylation of electron-deficient alkenes with tetraorganosilicon reagents and allylic carbonates based on Pd/Cu catalysis has been developed. This method affords a wide range of structurally diverse carbon skeletons from readily available starting materials, and tolerates various functional groups.
