1126784-57-3Relevant academic research and scientific papers
Radical catalysis of kumada cross-coupling reactions using functionalized grignard reagents
Manolikakes, Georg,Knochel, Paul
supporting information; experimental part, p. 205 - 209 (2009/04/10)
(Chemical Equation Presented) Palladium, radically different: A wide range of polyfunctional aryl- and heteroarylmagnesium reagents undergo fast Kumada cross-couplings (see scheme) with functionalized aryl bromides in the presence of a palladium catalyst and an alkyl iodide as additive. These reactions proceed by a radical pathway.
