112680-55-4

Upstream product

• 112680-54-3 (1S,2S,3S)-2-(3-oxo-trans-hex-1-enyl)-3-n-propyl-N-(tert-butyloxycarbonyl)cyclohexylamine 
• 112680-50-9 (1S,2S,6S)-(N-tosylamino)-6-n-propyl-1-<<2(S)-(methoxycarbonyl)pyrrolidin-1-yl>carbonyl>cyclohexane 
• 112680-51-0 (1S,2S,3S)-2-(hydroxymethyl)-3-n-propyl-N-tosyl-cyclohexylamine 
• 112680-48-5 6-n-propyl-1,2,3,10,11,11a(S)-hexahydro-5H-pyrrolo<2,1-c><1,4>benzodiazepine-5,11-dione 
• 112680-49-6 (5aS,6S,9aS,11aS)-perhydro-5H-pyrrolo<2,1-c><1,4>benzodiazepine-5,11-dione 
• 78756-21-5 (11aS)-6-methyl-1,2,3,10,11,11a-hexahydro-5H-pyrrolo<2.1-c><1,4>benzodiazepine-5,11-dione 
• 112680-53-2 (1S,2S,3S)-2-formyl-3-n-propyl-N-(tert-butyloxycarbonyl)cyclohexylamine 
• 112680-52-1 (1S,2S,3S)-2-(hydroxymethyl)-3-n-propyl-N-(benzyloxycarbonyl)cyclohexylamine 
• 24424-99-5 di-tert-butyl dicarbonate 

Relevant academic research and scientific papers

Enantioselective Total Synthesis of (+)-Perhydro-219A from an Anthranilic Acid Derivative

The first total synthesis of a trans-decahydroquinoline alkaloid derivative, (+)-perhydro-219A, is described.Key steps of the synthesis include the directed metalation-ethylation of 6-methylpyrrolobenzodiazepine-5,11-dione 2 to give the C(6)-n-propyl deri