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112681-16-0

(S)-2-isocyano-3-phenyl-N-((S)-1-phenyl-ethyl)-propionamide is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 112681-16-0 Structure

  • Basic information

    1. Product Name: (S)-2-isocyano-3-phenyl-N-((S)-1-phenyl-ethyl)-propionamide
    2. Synonyms: (S)-2-isocyano-3-phenyl-N-((S)-1-phenyl-ethyl)-propionamide
    3. CAS NO:112681-16-0
    4. Molecular Formula:
    5. Molecular Weight: 278.354
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 112681-16-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (S)-2-isocyano-3-phenyl-N-((S)-1-phenyl-ethyl)-propionamide(CAS DataBase Reference)
    10. NIST Chemistry Reference: (S)-2-isocyano-3-phenyl-N-((S)-1-phenyl-ethyl)-propionamide(112681-16-0)
    11. EPA Substance Registry System: (S)-2-isocyano-3-phenyl-N-((S)-1-phenyl-ethyl)-propionamide(112681-16-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 112681-16-0(Hazardous Substances Data)

112681-16-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 112681-16-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,2,6,8 and 1 respectively; the second part has 2 digits, 1 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 112681-16:
(8*1)+(7*1)+(6*2)+(5*6)+(4*8)+(3*1)+(2*1)+(1*6)=100
100 % 10 = 0
So 112681-16-0 is a valid CAS Registry Number.

112681-16-0Relevant articles and documents

Passerini reaction-amine deprotection-acyl migration peptide assembly: Efficient formal synthesis of cyclotheonamide c

Faure, Sophie,Hjelmgaard, Thomas,Roche, Stephane P.,Aitken, David J.

supporting information; experimental part, p. 1167 - 1170 (2009/08/07)

A short, convergent, formal total synthesis of cyclotheonamide C is described. The key linear pentapeptide intermediate is assembled at the same time as the elaboration of the α-hydroxyhomoarginine (H-hArg) residue via a three-component Passerini reaction

Scope and Limitations of the TiCl4-Mediated Additions of Isocyanides to Aldehydes and Ketones with Formation of α-Hydroxycarboxylic Acid Amides

Seebach, Dieter,Adam, Geo,Gees, Thomas,Schiess, Martin,Weigand, Wolfgang

, p. 507 - 518 (2007/10/02)

The adducts obtained from TiCl4 and achiral (8-12) or chiral, nonracemic (13-22) isocyanides are combined with aldehydes (aromatic or aliphatic) and ketones (acetone, cyclohexanone, acetophenone) to give, after aqueous workup, α-hydroxyamides (27-55) .The transformation is compatible with a variety of functional groups (aromatic and heterocyclic rings, amino, ether, ester, and amido groups, halides, and phosphonate substituents).The yields range from 14 to over 95percent (with the lower values in the case of more highly functionalised isocyanides).No diastereoselectivity is observed with chiral isocyanides.If the R groups of the isocyanide (R-NC) form a rather stable cation (t-alkyl or benzylic), cyanohydrins may result from the reaction, rather than the N-substituted α-hydroxyamides (see Scheme 2).

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