112684-58-9

Upstream product

• 1139-97-5 2,3,4,6-tetra-O-methyl-D-glucopyranose 
• 162119-07-5 (2S,3R,4R,5R)-2,3,4,6-Tetrakis-benzyloxy-5-hydroxy-hexanal O-methyl-oxime 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 300548-00-9 5-O-(1H-imidazol-1-yl-thioxomethyl)-2,3,4,6-tetrakis-O-(phenylmethyl)-D-xylo-hexos-5-ulose 1-(O-methyloxime) 

Relevant academic research and scientific papers

Radical cyclization in heterocycle synthesis. Part 9: A novel synthesis of aminocyclitols and related compounds via stannyl radical cyclization of oxime ethers derived from sugars

Stannyl radical addition-cyclization of oxime ethers derived from D-glucose, D-galactose, and D-xylose proceeded smoothly to afford alkoxyamino alcohols which were effectively converted into two types of glycosidase inhibitors or its candidates such as aminocyclitols, 1-deoxynojirimycin, and 1-deoxygalactostatin via reductive ring-expansion of trans alkoxyamino alcohols. (C) 2000 Elsevier Science Ltd.